Liling grew up in South West Sydney and completed her MBBS at Western Sydney University in 2011. She finished her internship and residency at Westmead Hospital before undertaking her GP training in the Blue Mountains and completing her fellowship in 2016. Liling has completed the Diploma in Child Health and the FPAA National Certificate in Reproductive and Sexual Health for Doctors with subsequent IUD training. She has special interest in Women's Health, paediatrics and chronic care.